Mössbauer spectroscopy : applications in chemistry, biology, and nanotechnology

edited by Virender K. Sharma, Göstar Klingelhöfer, Tetsuaki Nishida

A one-stop reference for determining the oxidation states of elements so that oxidation eduction chemistry can be studied across a wide variety of systems, this book presents advances in the field from the last two decades. Beginning with a detailed theoretical description of Mossbauer spectroscopy, followed by an extensive treatment of its use in applied areas such as synchrotron radiation, biotechnology, and nanoparticle analysis, the book discusses future opportunities for the further development of this technique. Designed for spectroscopists, inorganic, physical, analytical, and solid-state chemists and other researchers.

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  • Preface Chapter 1 In-Situ Mossbauer Spectroscopy with Synchrotron Radiation on Thin Films S Stankov, T Slezak, M Zajac, M Slezak, M Sladecek, R Rohlsberger, B. Sepiol, G Vogl, N Spiridis, J Lazewski, K Parlinski, and J Korecki 1 1 Introduction 1.2 Instrumentation 1.3 Synchrotron radiation-based Mossbauer techniques References Chapter 2 Mossbauer Spectroscopy in Studying Electronic Spin and Valence States of Ironin the Earth's Lower Mantle Jung-Fu Lin, Zhu Mao, and Ercan E Alp 2.1 Introduction 2.2 Synchrotron Mossbauer Spectroscopy at High Pressures and Temperatures 2.3 Crystal Field Theory on the 3 d Electronic States 2.4 Conclusion Acknowledgments References Chapter 3 In-beam Mossbauer Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction Yoshio Kobayashi 3.1 I ntroduction 3.257Mn (--> 57 Fe) Implantation Mossbauer Spectroscopy 3.3 Neutron in-beam Mossbauer Spectroscopy 3 .4 Summary References Radionuclides Chapter 4 Lanthanides( 151 Eu and 155 Gd)-Mossbauer Spectroscopic Study of Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model Nakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda 4.1 Introduction 4.2Defect-crystal-Chemistry (DCC) Lattice-parameter Model 4.3 Lns Mossbauer and Lattice-parameter Data of DF Oxides 4.4 DCC-Model Lattice-parameter and Lns-Mossbauer Data Analysis Conclusion References Chapter 5 Mossbauer and Magnetic Study of Neptunyl(+1) Complexes T Nakamoto, A Nakamura and M Takeda 5.1 Introduction 5.2 237Np Mossbauer Spectroscopy 5.3 Magnetic Property of Neptunyl Monocation (NpO 2 + ) 5.4 Mossbauer and Magnetic Study of Neptunyl(+1) Complexes 5.5 Discussion Conclusion Acknowledgment References Chapter 6 Mossbauer Spectroscopy of 161 Dy in Dysprosium Dicarboxylates M Takahashi, C I Wynter, B R Hillery, Virender K Sharma, D Quarless, Leopold May, T Misu, S G Sobel, M Takeda, and E Brown 6.1 Introduction 6.2 Experimental Methods 6.3 Results and Discussion 6.4 Acknowledgment References Chapter 7 Study of Exotic Uranium Compounds using 238 U Mossbauer Spectroscopy Satoshi Tsutsui 1,2 and Masami Nakada 2 7.1 Introduction 7.2 Determination of Nuclear g -factor in the Excited State of 238 U Nuclei 7.3 Application of 238 U Mossbauer Spectroscopy to Heavy Fermion 7.4 Application to Two-dimensional (2D) Fermi Surface System of Uranium Dipnictides Summary Acknowledgment References Spin Dynamics Chapter 8 Reversible Spin-state Switching Involving a Structural Change Satoru Nakashima 8.1 Introduction 8.2Three Assembled Structures of Fe(NCX) 2 (bpa) 2 (X=S, Se) and Their Structural Change by Desorption of Propanol Molecules 8.3 Occurrence of Spin-crossover Phenomenon in Assembled Complexes Fe(NCX) 2 (bpa) 2 (X=S, Se, BH 3 ) by Enclathrating Guest Molecules 8.4 Reversible Structural Change of Host Framework of Fe(NCS) 2 (bpp) 2 *2(benzene) Triggered By Sorption of Benzene Molecules 8.5 Reversible Spin-state Switching Involving a Structural Change of Fe(NCX) 2 (bpp) 2 *2(benzene) (X=Se, BH 3 ) Triggered By Sorption of Benzene Molecules 8.6 Conclusion References Chapter 9 Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge N Kokima and A Sugahara 9.1 Introduction 9.2 Photo-induced Spin-crossover Phenomena 9 3 Charge Transfer Phase Transition 9 4 Spin Equilibrium and Succeeding Phenomena Fluctuation References Chapter 10 Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin State Mikio Nakamura and Masashi Takahashi 10.1 Introduction 10.2 Methodology to Obtain Pure Intermediate-Spin Complexes 10.3 Spin Crossover Involving the Intermediate-Spin State 10.4 Spin Crossover Triangle in Iron(III) Porphyrins 10.5 Conclusion Acknowledgments References Chapter 11 Tin(II) Lone Pair Stereoactivity: Influence on Structures and Properties, and Mossbauer Spectroscopic Properties Georges Denes 1 , M Cecilia Madamba 1 , Hocine Merazig 2 and Abdualhafed Muntasar 11.1 Introduction 11.2 Experimental 11.3 Crystal Structures 11.4 Tin Electronic Structure and Mossbauer Spectroscopy 11.5 Application to the Structural Determination of alpha-SnF 2 11.6 Application to the Structural Determination of the Highly Layered Structures of alpha-PbSnF 4 and BaSnF 4 11.7 Application to the Structural Study of Disordered Phases 11.8 Lone Pair Stereoactivity and Material Properties 11.9 Conclusion Acknowledgments References Biological Applications Chapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering: Applications to Bioinorganic Chemistry Yisong Guo, Yoshitaka Yoda, Xiaowei Zhang, Yuming Xiao, Stephen P Cram 12.1 Introduction 12.2 Technical Background 12.3 Applications in Bioinorganic Chemistry 12.4 Summary and Prospects Acknowledgment References Chapter 13 Mossbauer Spectroscopy in Biological and Biomedical Research Alexander A Kamnev 1, *, Krisztina Kovacs 2 , Irina V Alenkina 3 , and Michael I. Oshtrakh 13.1 Introduction 13.2 Microorganisms-related studies 13.3 Plants 13.4 Enzymes 13.5 Hemogoblin 13.6 Ferritin and Hemosiderin 13.7 Tissues 13.8 Pharmaceutical Products 13.9 Conclusions Acknowledgments References Chapter 14 Controlled Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments) Vladimir I Vysotskii and Alla A Kornilova 14.1 Introduction to the Problem of Controlled Spontaneous Gamma-decay 14.2 General Consideration 14.3 Controlled Spontaneous Gamma-decay of Excited Nucleus in the System of Mutually Uncorrelated Modes of Electromagnetic Vacuum 14.4 Spontaneous Gamma-decay in the System of Synchronized Modes of Electromagnetic Vacuum 14.5 Experimental Study of the Phenomenon of Controlled Gamma-decay of Mossbauer Nuclei 14.6 Experimental Study of the Phenomenon of Controlled Gamma-decay by Investigation of Space Anisotropy and Self-focusing of Mossbauer Radiation 14.7 Direct Experimental Observation and Study of the Process of Controlled Radioactive and Excited Nuclei Radiative Gamma-decay by the Delayed Gamma-gamma Coincidence Method 14.8 Conclusion References Chapter 15 Natural's Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of High-Valent Fe Intermediates Kednerlin Dornevil and Aimin Liu 15.1 Two Oxidizing Equivalents Stored at a Ferric Heme 15.2 Oxidation of L-Tryptophan by Heme-Based Enzymes 15.3 The Chemical Reaction Catalyzed by MauG 15.4 A High-Valent bis -Fe(IV) Intermediate in MauG 15.5 High-Valent Fe Intermediate of Tryptophan 2,3-Dioxygenase 15.6 Concluding Remarks References Chapter 16 Iron in Neurodegeneration Jolanta Galazka-Friedman, Erika R Bauminger, and Andrzej Friedman 16.1 Introduction 16.2 Neurodegeneration and Oxidative Stress 16.3 Mossbauer Studies of Healthy Brain Tissue 16.4 Properties of Ferritin and Hemosiderin Present in Healthy Brain Tissue 16.5 Concentration of Iron Present in Healthy and Diseased Brain Issue 16.6 Asymmetry of the Mossbauer Spectra of Healthy and Diseased Brain Tissue 16.7 Conclusion -- the Possible Role of Iron in Neurodegeneration References Chapter 17 Emission ( 57 Co) Mossbauer Spectroscopy: Biology-related Applications, Potentials and Prospects Alexander A Kamnev 17.1 Introduction 17.2 Methodology 17.3 Microbiological Applications 17.4 Enzymological Applications 17.5 Conclusions and Outlook Acknowledgments References Iron Oxides Chapter 18 Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal Processes Jiri Tucek, Libor Machala, Jiri Frydrych, Jiri Pechousek, and Radek Zboril 18.1 Introduction 18.2 Polymorphs of Iron (III) Oxide, Their Crystal Structures, Magnetic Properties, and Polymorphous Phase Transformations 18.3 Use of 57 Fe Mossbauer Spectroscopy in Monitoring Solid State Reaction Mechanisms towards Iron Oxides 18.4 Various Mossbauer Spectroscopy Techniques in Study of Applications Related to Nanocrystalline Iron Oxides 18.5 Conclusion Acknowledgment References Chapter 19 Transmission and Emission 57 Fe Mossbauer Studies on Perovskites and Related Oxide Systems Zoltan Homonnay and Zoltan Nemeth 19.1 Introduction 19.2 Study of high- T c superconductors 19.3 Study of Strontium ferrate and its substituted analogues 19.4 Pursuing Colossal Magnetoresistance in Doped Lanthanum Cobaltates References Chapter 20 Enhancing the Possibilities of 57 Fe Mossbauer Spectrometry to Study the Inherent Properties of Rust Layers Karen E Garcia, Cesar A Barrero, Alvaro L Morales, and Jean-Marc Greneche 20.1 Introduction 20.2 Mossbauer Characterization of Some Iron Phases Presented in the Rust Layers 20.3 Determining Inherent Properties of Rust Layers by Mossbauer Spectrometry 20.4 Final Remarks Acknowledgments References Chapter 21 Application of Mossbauer Spectroscopy in Nanomagnetics Lakshmi Nambakkat 21.1 Introduction 21.2 Spinel Ferrites 21.3 Nano Sized Fe-Al Alloys Synthesized by High Energy Ball Milling 21.4 Magnetic Thin Films/Multilayer Systems: 57 Fe/Al MLS Conclusion Acknowledgment References Chapter 22 Mossbauer Spectroscopy and Surface Analysis Jose F Marco, J Ramon Gancedo, Matteo Monti and Juan de la Figuera 22.1 Introduction 22.2 The Physical Basis: How and Why Electrons Appear in Mossbauer Spectroscopy 22.3 Increasing Surface Sensitivity in Electron Mossbauer Spectroscopy 22.4 The Practical Way: Experimental Low Energy Electron Mossbauer Spectroscopy 22.5 Mossbauer Surface Imaging Techniques 22.6 Recent Surface Mossbauer Studies in an "ancient" Material: Fe 3 O 4 Acknowledgments References Chapter 23 57 Fe Mossbauer Spectroscopy in the Investigation of the Precipitation of Iron Oxides Svetozar Music, Mira Ristic, and Stjepko Krehula 23.1 Introduction 23.2 Complexation of Iron Ions by Hydrolysis 23.3 Precipitation of Iron Oxides by Hydrolysis Reactions 23.4 Precipitation of Iron Oxides from Dense -FeOOH Suspensions 23.5 Precipitation and Properties of Some Other Iron Oxides 23.6 Influence of Cations on the Precipitation of Iron Oxides Acknowledgment References Chapter 24 Ferrates (IV, V, and VI): Mossbauer Spectroscopy Characterization Virender K Sharma, Yurii Perfiliev, Radek Zboril, Libor Machala, and Clive Wynter 24.1 Introduction 24.2 Spectroscopic Characterization 24.3 Mossbauer Spectroscopy Characterization Acknowledgments References Chapter 25 Characterization of Dilute Iron-Doped Yttrium Aluminum Garnets by Mossbauer Spectrometry Kiyoshi Nomura and Zoltan Nemeth 25.1 Introduction 25.2 Sample Preparations by sol-gel Method 25.3 X-ray Diffraction and EXAFS Analysis 25.4 Magnetic Properties 25.5 Mossbauer Analysis of YAG Doped with Dilute Iron 25.6 Micro-discharge Treatment of Iron Doped YAG Conclusion Acknowledgment References Industrial Applications Chapter 26 Some Mossbauer Studies of Fe-As Based High Temperature Superconductors Amar Nath and Airat Khasanov 26.1 Introduction 26.2 Experimental 26.3 Where Do the Injected Electrons Go? 26.4 New Electron-rich Species in Ni-doped Single Crystals: Is it Superconducting? 26.5 Can O 2 play an Important Role? Acknowledgment References Chapter 27 Mossbauer Study of New Electrically Conductive Glass Tetsuaki Nishida and Shiro Kubuki 27.1 Introduction 27.2 Structural Relaxation of Electrically Conductive Vanadate Glass Acknowledgments References Chapter 28 Applications of Mossbauer Spectroscopy in the Study of Lithium Battery Materials Ricardo Alcantara, Pedro Lavela, Carlos Perez Vicente, Jose L Tirado 28.1 Introduction 28.2 Cathode Materials for Li-ion Batteries 28.3 Anode Materials for Li-ion Batteries Conclusions Acknowledgment References Chapter 29 Mossbauer Spectroscopic Investigations of Novel Bimetal Catalysts for Preferential CO Oxidation in H 2 Wansheng Zhang, Junhu Wang, Kuo Liu, Jie Jin, and Tao Zhang 29.1 Introduction 29.2 Experimental Section 29.3 Results and Discussion Conclusion Acknowledgments References Chapter 30 The use of Mossbauer Spectroscopy in Coal Research-Is it Relevant or Not? F B Waanders 30.1 Introduction 30.2 Experimental Procedures 30.3 Results and Discussion Conclusions References Environmental Applications Chapter 31 Water Purification and Characterization of Recycled Iron-Silicate Glass Shiro Kubuki and Tetsuaki Nishida 31.1 Introduction 31.2 Property and Structure of Recycled Silicate Glasses 31.3 Summary Reference Chapter 32 Mossbauer Spectroscopy in the Study of Laterite Mineral Processing Eamonn Devlin, Michail Samouhos, Charalabos Zografidis 32.1 Introduction 32.2 Conventional Processing 32.3 Microwave Processing Reference

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書名 Mössbauer spectroscopy : applications in chemistry, biology, and nanotechnology
著作者等 西田 哲明
Klingelhofer Gostar
Klingelhöfer Göstar
Nishida Tetsuaki
Sharma Virender K.
出版元 Wiley
刊行年月 c2013
ページ数 xxiv, 631 p.
大きさ 29 cm
ISBN 9781118057247
NCID BB19011036
※クリックでCiNii Booksを表示
言語 英語
出版国 アメリカ合衆国