Advances in supramolecular chemistry : a research annual  vol. 1 ~ vol. 7

editor, George W. Gokel

This volume presents a variety of articles that encompass the broad scope of supramolecular chemistry. Reusch's chapter covers biological channel compounds, while the work of Hall and Kirkovits looks into their synthetic counterparts. Metal ion sensors, calixarenes and "crystal engineering" are described by pioneers in these fields. This work, whilst current and authoritative, shows us that much remains to be undertaken and understood. It is hoped that this volume will be of interest to those who wish to fill these gaps; scientists already in the field and those who may see extensions of their own work that will bring them into it.

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In this volume, inorganic, organic, and bioorganic chemistry are represented in contributions from around the world. Pioneering work in self-assembled structures organized by the use of transition metals is described in chapter 1, followed by details of extensive studies of self-assembled structures formed from various biomolecules in chapter 2. The next two chapters describe the formation of spherical molecular containers and their understanding of such structures based on Platonic and Archimedean solids, and the fascinating family of synthetic peptide receptors and the interactions that can be explored using these host molecules. In chapter 5, a mixture of computational chemistry, drug design, and synthetic organic and inorganic chemistry in the development of superoxide dismutase mimics is described. The final two chapters discuss the bioorganic and supramolecular principles required for the design of synthetic artificial enzymes, and the supramolecular self-assembly and its possible role in the origin of life. It is hoped that this broad, international view of supramolecular chemistry and the many directions it leads will be of interest to those already in the field. It is also hoped that those outside the field may see extensions of their own work that will bring them into it.

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[目次]

  • Preface (G.W. Gokel). Supramolecular photoionic devices: photoinduced electron transfer (PET) systems with switchable luminescence output (A. Prasanna de Silva et al.). Molecular recognition in chemistry and biology as viewed from enthalpy-entropy compensation effect: global understanding of supramolecular interactions (Y. Inoue, T. Wada). Anion binding by sapphyrins (J.L. Sessler et al.). Avidin-biotin supramolecular complexation for biosensor applications (J. Anzai, Y. Osa). Artificial ion channels (Y. Kobuke). Chemical sensing based on membranes with supramolecular functions of biomimetic and biological origin (K. Odashima et al.). Supramolecular anion receptors (K.Travis et al.). Index.

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[目次]

  • Supramolecular assemblies in natural and artificial ion channels (G.J. Kirkovits, C.D. Hall). Ion recognition and transport by Poly-(R)-3-hyroxybutanoates and inorganic polyphosphates (R.M. Reusch). Functionalized macrocyclic ligands as sensory molecules for metal ions (G. Xue et al.). Chirality in calixarenes and calixarene assemblies (M. Vysotsky et al.). From molecules to crystals: supramolecular synthesis of solids (B. Moulton, M.J. Zaworotko). Index.

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[目次]

  • List of contributors. Preface. Molecular self-assemblies through coordination: macrocycles, catenanes, cages, and tubes. Chiral self-assembled structures from biomolecules and synthetic analogues. Spherical molecular containers: from discovery to designod). Synthetic peptide receptors: noncovalent interactions involving peptides. Rational design of synthetic enzymes and their potential utility as human pharmaceuticals: development of manganese(II)-based superoxide dismutase mimics. Designing active sites of synthetic artificial enzymes. The relevance of supramolecular chemistry for the origin of life. Index.

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この本の情報

書名 Advances in supramolecular chemistry : a research annual
著作者等 Gokel, George W.
巻冊次 vol. 1
vol. 2
vol. 3
vol. 4
vol. 5
vol. 6
vol. 7
出版元 JAI Press
刊行年月 1990-
ページ数 v. <1- >
大きさ 24 cm
ISBN 0762305576
0762306785
1559383291
1559385464
1559387947
1559381817
ISSN 10687459
NCID BA11600182
※クリックでCiNii Booksを表示
言語 英語
出版国 アメリカ合衆国
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