Organic chemistry in colour

P.F. Gordon, P. Gregory

[目次]

  • 1 The Development of Dyes.- 1.1 Introduction.- 1.2 Pre-Perkin Era - The Natural Dyes.- 1.2.1 Introduction.- 1.2.2 Yellow Dyes.- 1.2.3 Red Dyes.- 1.2.4 Purple Dyes.- 1.2.5 Blue Dyes.- 1.2.6 Black Dyes.- 1.3 Perkin and Beyond - The Synthetic Dyes.- 1.3.1 Introduction.- 1.3.2 Perkin's Discovery of Mauveine.- 1.3.3 The Post-Mauveine Era.- 1.3.4 Kekule's Contribution.- 1.3.5 Alizarin.- 1.3.6 Indigo.- 1.3.7 The Introduction of Novel Chromogens.- 1.4 Future Trends.- 1.5 Summary.- 1.6 Bibliography.- 2 Classification and Synthesis of Dyes.- 2.1 Introduction.- 2.2 Classification of Dyes.- 2.2.1 Azo Dyes.- 2.2.2 Anthraquinone Dyes.- 2.2.3 Vat Dyes.- 2.2.4 Indigoid Dyes.- 2.2.5 Polymethine Dyes.- 2.2.6 Aryl-Carbonium Dyes.- 2.2.7 Phthalocyanine Dyes.- 2.2.8 Nitro Dyes.- 2.2.9 Miscellaneous Dyes.- 2.3 Synthesis of Dye Intermediates.- 2.3.1 Synthesis of Aromatic Carbocycles.- 2.3.2 Synthesis of Aromatic Heterocycles.- 2.4 Synthesis of Dyes.- 2.4.1 Azo Dyes.- 2.4.2 Anthraquinone Dyes.- 2.4.3 Vat Dyes.- 2.4.4 Phthalocyanine Dyes.- 2.4.5 Indigoid Dyes.- 2.4.6 Polymethine Dyes.- 2.4.7 Di- and Tri-Arylcarbonium Dyes.- 2.5 Summary.- 2.6 Bibliography.- 3 Azo Dyes.- 3.1 Introduction.- 3.2 Basic Structure of Azo Dyes.- 3.3 Tautomerism.- 3.3.1 Tautomerism of Hydroxyazo Dyes - Azo-Hydrazone Tautomerism.- 3.3.2 Hydroxyazo Dyes of the Naphthalene Series.- 3.3.3 Hydroxyazo Dyes of the Benzene Series.- 3.3.4 Tautomerism of Aminoazo Dyes - Amino-imino Tautomerism..- 3.3.5 Protonated Azo Dyes - Azonium-Ammonium Tautomerism.- 3.4 Metal Complex Azo Dyes.- 3.4.1 Introduction.- 3.4.2 Medially Metallised Azo Dyes - Nature of the Bonding by the Azo Group.- 3.4.3 Types of Dyes and their Stability.- 3.4.4 Structure and Stereochemistry.- 3.4.5 Conimercial Uses of Metal Complex Azo Dyes.- 3.4.6 Properties of the Metallised Dyes.- 3.4.7 Terminally Metallised Dyes.- 3.5 Colour and Constitution.- 3.5.1 Introduction.- 3.5.2 Early Theories.- 3.5.3 Modern Theories.- 3.5.4 Experimental Observations. Monoazo Dyes - Derivatives of 4-Aminoazobenzene.- 3.5.5 Application of VB and MO Theories.- 3.5.6 Protonated Azo Dyes.- 3.5.7 Azo-Hydrazone Tautomers.- 3.5.8 Polyazo Dyes.- 3.5.9 Steric Effects.- 3.6 Summary.- 3.7 Bibliography.- 4 Anthraquinone Dyes.- 4.1 Introduction.- 4.2 Structure of Anthraquinone Dyes.- 4.3 Tautomerism.- 4.3.1 Tautomerism of Hydroxyanthraquinone Dyes.- 4.3.2 Reduced Hydroxyanthraquinone Dyes - Leuco-Quinizarin.- 4.3.3 Aminoanthraquinone Dyes.- 4.3.4 Reduced Aminoanthraquinone Dyes.- 4.4 Protonated and Ionised Anthraquinone Dyes.- 4.4.1 Introduction.- 4.4.2 Anthraquinone.- 4.4.3 Aminoanthraquinone Dyes.- 4.4.4 Hydroxyanthraquinone Dyes.- 4.4.5 Aminohydroxyanthraquinone Dyes.- 4.5 Metal Complexed Anthraquinone Dyes.- 4.5.1 Introduction.- 4.5.2 Commercial Dyes.- 4.5.3 Structure and Properties.- 4.6 Colour and Constitution.- 4.6.1 Introduction.- 4.6.2 Experimental Results.- 4.6.3 VB/MO Explanation of Colour and Constitution.- 4.6.4 Steric Effects.- 4.7 Summary.- 4.8 Bibliography.- 5 Miscellaneous Dyes.- 5.1 Introduction.- 5.2 Vat Dyes.- 5.2.1 Introduction.- 5.2.2 The Anthraquinonoid Vat Dyes.- 5.2.3 Sulphur-containing Vat Dyes.- 5.2.4 Colour and Constitution of Anthraquinonoid Vat Dyes.- 5.3 Indigoid Dyes.- 5.3.1 Introduction.- 5.3.2 Structure and Unusual Features of Indigo.- 5.3.3 Colour and Constitution of Indigoid Dyes.- 5.3.4 Other Indigoid Dyes.- 5.3.5 Protonation and Ionisation.- 5.3.6 Commercial Indigoid Dyes.- 5.4 The Phthalocyanines.- 5.4.1 Introduction.- 5.4.2 The Discovery of the Phthalocyanines.- 5.4.3 Elucidation of the Structure of Phthalocyanine.- 5.4.4 Colour and Constitution of Porphyrins and Phthalocyanines.- 5.4.5 Copper Phthalocyanine Dyes.- 5.5 Polymethine Dyes.- 5.5.1 Introduction.- 5.5.2 Oxonols and Merocyanines.- 5.5.3 Cyanine Dyes and their Derivatives.- 5.5.4 Colour and Constitution.- 5.6 Di- and Tri-aryl Carbonium Dyes and their Derivatives.- 5.6.1 Introduction.- 5.6.2 Structural Interrelationships.- 5.6.3 General Colour-Structure Properties.- 5.6.4 Steric Effects.- 5.6.5 Phenolphthalein.- 5.6.6 Heterocyclic Derivatives of Di- and Tri-phenylmethanes.- 5.7 Nitro (and Nitroso) Dyes.- 5.7.1 Introduction.- 5.7.2 Nitrodiphenylamine Dyes.- 5.7.3 Nitroso Dyes.- 5.8 Summary.- 5.9 Bibliography.- 6 Application and Fastness Properties of Dyes.- 6.1 Introduction.- 6.2 Textile Fibres - Types and Structures.- 6.2.1 Introduction.- 6.2.2 Natural Fibres.- 6.2.3 Semi-Synthetic Fibres.- 6.2.4 Synthetic Fibres.- 6.3 Application and Wet Fastness of Dyes.- 6.3.1 Introduction.- 6.3.2 Physical Adsorption.- 6.3.3 Solid Solutions.- 6.3.4 Insoluble Aggregates within the Fibre.- 6.3.5 Ionic Bonds.- 6.3.6 Covalent Bonds.- 6.4 Light Fastness of Dyes.- 6.4.1 Introduction.- 6.4.2 Test Methods.- 6.4.3 Basic Photochemical Principles.- 6.4.4 Mechanism of Fading.- 6.4.5 Effect of Aggregation on Light Fastness.- 6.4.6 Catalytic Fading.- 6.4.7 Phototendering of Dyed Fibre.- 6.5 Photochromism.- 6.6 Heat Fastness of Dyes.- 6.7 Bleach Fastness of Dyes.- 6.8 Metamerism.- 6.9 Solvatochromism.- 6.10 Summary.- 6.11 Bibliography.- Appendix I.- Appendix II.- Author Index.

「Nielsen BookData」より

この本の情報

書名 Organic chemistry in colour
著作者等 Gordon, P. F.
Gregory, P.
Gregory P J
Gregory P.
Gordon Paul Francis
出版元 Springer-Verlag
刊行年月 c1987
版表示 illustrated ed
ページ数 xi, 322 p.
大きさ 25 cm
ISBN 0387172602
3540172602
NCID BA01136996
※クリックでCiNii Booksを表示
言語 英語
出版国 ドイツ
この本を: 
このエントリーをはてなブックマークに追加

Yahoo!ブックマークに登録
この記事をクリップ!
Clip to Evernote
このページを印刷

外部サイトで検索

この本と繋がる本を検索

ウィキペディアから連想