Collected papers of Wallace Hume Carothers on high polymeric substances; ed. by H. Mark [and] G. Stafford Whitby. New York, Interscience Publishers, 1940
[and] G. Stafford Whitby. New York, Interscience Publishers, 1940
I. An Introduction to the General Theory of Condensation Polymers / 4
II. Polyesters / 17
III. Glycol Esters of Carbonic Acid / 29
IV. Ethylene Succinates / 42
V. Glycol Esters of Oxalic Acid / 54
VI. Adipic Anhydride / 63
VII. Normal Paraffin Hydrocarbons of High Molecular Weight Prepared by the Action of Sodium on Decamethylene Bromide / 68
VIII. Amides from ε-Aminocaproic Acid / 78
IX. Polymerization / 81
X. The Reversible Polymerization of Six-Membered Cyclic Esters / 141
XI. The Use of Molecular Evaporation as a Means for Propagating Chemical Reactions / 154
XII. Linear Superpolyesters / 156
XIII. Polyamides and Mixed Polyester-Polyamides / 165
XIV. A Linear Superpolyanhydride and a Cyclic Dimeric Anhydride from Sebacic Acid / 168
XV. Artificial Fibers from Synthetic Linear Condensation Superpolymers / 179
XVI. A Polyalcohol from Decamethylene Dimagnesium Bromide / 190
XVII. Friedel-Crafts Syntheses with the Polyanhydrides of the Dibasic Acids / 192
XVIII. Polyesters from ω-Hydroxydecanoic Acid / 195
XIX. Many-Membered Cyclic Anhydrides(1) / 202
XX. Many-Membered Cyclic Esters / 212
XXI. Physical Properties of Macrocyclic Esters and Anhydrides.New Types of Synthetic Musks / 221
XXII. Stereochemistry and Mechanism in the Formation and Stability of Large Rings / 225
XXIII. ε-Caprolactone and Its Polymers / 235
XXIV. Cyclic and Polymeric Formals / 240
XXV. Macrocyclic Esters / 248
XXVI. Meta and Para Rings / 259
XXVII. Polydecamethylene Oxide / 263
XXVIII. Preparation of Macrocyclic Lactones by Depolymerization / 265
Part Two
Acetylene Polymers and Their Derivatives / 271
I. Introduction by G.Stafford Whitby / 273
II. A New Synthetic Rubber:Chloroprene and Its Polymers / 281
III. The Addition of Hydrogen Chloride to Vinylacetylene / 306
IV. The Addition of Hydrogen Bromide to Vinylacetylene,Bromoprene and Dibromobutene / 311
V. The Polymerization of Bromoprene(Third Paper on New Synthetic Rubbers) / 314
VI. Vinylethinylmagnesium Bromide and Some of Its Reactions / 321
VII. Sodium Vinylacetylide and Vinylethinylcarbinols / 323
VIII. α-Alkyl-β-Vinylacetylenes / 329
IX. 1-Alkyl-2-chloro-1,3-butadienes and their Polymers(Fourth Paper on New Synthetic Rubbers) / 331
X. The Chlorination of the Hydrochlorides of Vinylacetylene / 335
XI. Dichloro-2,3-butadiene-1,3 and Trichloro-1,2,3-butadiene-1,3 / 340
XII. The Addition of Thio-ρ-cresol to Divinylacetylene / 344
XIII. The Action of Chlorine on Dinvinylacetylene / 348
XIV. The Dihydrochloride of Divinylacetylene / 357
XV. Halogen-4-butadienes-1,2.The Mechanism of 1,4-Addition and of α,γ-Rearrangement / 361
XVI. The Preparation of Orthoprenes by the Action of Grignard Reagents on Chloro-4-butadiene-1,2 / 368
XVII. Mercury Derivatives of Vinylacetylene / 372
XVIII. 1-Halogen-2-vinylacetylenes / 375
XIX. The Structure of Divinylacetylene Polymers / 378
XX. The Addition of Alcohols to Vinylacetylene,etc / 381
XXI. Homologs of Chloroprene and Their Polymers(Second Paper on New Synthetic Rubbers) / 384
XXII. The Synthetic Rubber Problem / 391
Part Three
Miscellaneous Papers / 399
I. Association Polymerization and the Properties of Adipic Anhydride / 401
II. Ueber die angeblichen Isomerien bei cyclischen Oxalsaeure-estern / 402
III. ε-Caprolactone / 407
IV. Polymers and Polyfunctionality / 409
Bibliography and Patents / 423
Authors Index / 433
Subject Index / 439
「国立国会図書館デジタルコレクション」より
書名
Collected papers of Wallace Hume Carothers on high polymeric substances; ed. by H. Mark [and] G. Stafford Whitby. New York, Interscience Publishers, 1940
著作者等
Carothers, Wallace Hume
シリーズ名
High polymers; a series of monographs on the chemistry, physics and technology of high polymeric substances; v. 1
巻冊次
[and] G. Stafford Whitby. New York, Interscience Publishers, 1940
