Collected papers of Wallace Hume Carothers on high polymeric substances; ed. by H. Mark [and] G. Stafford Whitby. New York, Interscience Publishers, 1940  [and] G. Stafford Whitby. New York, Interscience Publishers, 1940

[目次]

  • CONTENTS
  • Introduction to the Series,"High Polymers" / 5
  • Introduction to Volume I / 8
  • Table of Contents / 13
  • Biography by Roger Adams / 15
  • Part One
  • Studies on Polymerization and Ring Formation / 1
  • Introduction by H.Mark / 3
  • I. An Introduction to the General Theory of Condensation Polymers / 4
  • II. Polyesters / 17
  • III. Glycol Esters of Carbonic Acid / 29
  • IV. Ethylene Succinates / 42
  • V. Glycol Esters of Oxalic Acid / 54
  • VI. Adipic Anhydride / 63
  • VII. Normal Paraffin Hydrocarbons of High Molecular Weight Prepared by the Action of Sodium on Decamethylene Bromide / 68
  • VIII. Amides from ε-Aminocaproic Acid / 78
  • IX. Polymerization / 81
  • X. The Reversible Polymerization of Six-Membered Cyclic Esters / 141
  • XI. The Use of Molecular Evaporation as a Means for Propagating Chemical Reactions / 154
  • XII. Linear Superpolyesters / 156
  • XIII. Polyamides and Mixed Polyester-Polyamides / 165
  • XIV. A Linear Superpolyanhydride and a Cyclic Dimeric Anhydride from Sebacic Acid / 168
  • XV. Artificial Fibers from Synthetic Linear Condensation Superpolymers / 179
  • XVI. A Polyalcohol from Decamethylene Dimagnesium Bromide / 190
  • XVII. Friedel-Crafts Syntheses with the Polyanhydrides of the Dibasic Acids / 192
  • XVIII. Polyesters from ω-Hydroxydecanoic Acid / 195
  • XIX. Many-Membered Cyclic Anhydrides(1) / 202
  • XX. Many-Membered Cyclic Esters / 212
  • XXI. Physical Properties of Macrocyclic Esters and Anhydrides.New Types of Synthetic Musks / 221
  • XXII. Stereochemistry and Mechanism in the Formation and Stability of Large Rings / 225
  • XXIII. ε-Caprolactone and Its Polymers / 235
  • XXIV. Cyclic and Polymeric Formals / 240
  • XXV. Macrocyclic Esters / 248
  • XXVI. Meta and Para Rings / 259
  • XXVII. Polydecamethylene Oxide / 263
  • XXVIII. Preparation of Macrocyclic Lactones by Depolymerization / 265
  • Part Two
  • Acetylene Polymers and Their Derivatives / 271
  • I. Introduction by G.Stafford Whitby / 273
  • II. A New Synthetic Rubber:Chloroprene and Its Polymers / 281
  • III. The Addition of Hydrogen Chloride to Vinylacetylene / 306
  • IV. The Addition of Hydrogen Bromide to Vinylacetylene,Bromoprene and Dibromobutene / 311
  • V. The Polymerization of Bromoprene(Third Paper on New Synthetic Rubbers) / 314
  • VI. Vinylethinylmagnesium Bromide and Some of Its Reactions / 321
  • VII. Sodium Vinylacetylide and Vinylethinylcarbinols / 323
  • VIII. α-Alkyl-β-Vinylacetylenes / 329
  • IX. 1-Alkyl-2-chloro-1,3-butadienes and their Polymers(Fourth Paper on New Synthetic Rubbers) / 331
  • X. The Chlorination of the Hydrochlorides of Vinylacetylene / 335
  • XI. Dichloro-2,3-butadiene-1,3 and Trichloro-1,2,3-butadiene-1,3 / 340
  • XII. The Addition of Thio-ρ-cresol to Divinylacetylene / 344
  • XIII. The Action of Chlorine on Dinvinylacetylene / 348
  • XIV. The Dihydrochloride of Divinylacetylene / 357
  • XV. Halogen-4-butadienes-1,2.The Mechanism of 1,4-Addition and of α,γ-Rearrangement / 361
  • XVI. The Preparation of Orthoprenes by the Action of Grignard Reagents on Chloro-4-butadiene-1,2 / 368
  • XVII. Mercury Derivatives of Vinylacetylene / 372
  • XVIII. 1-Halogen-2-vinylacetylenes / 375
  • XIX. The Structure of Divinylacetylene Polymers / 378
  • XX. The Addition of Alcohols to Vinylacetylene,etc / 381
  • XXI. Homologs of Chloroprene and Their Polymers(Second Paper on New Synthetic Rubbers) / 384
  • XXII. The Synthetic Rubber Problem / 391
  • Part Three
  • Miscellaneous Papers / 399
  • I. Association Polymerization and the Properties of Adipic Anhydride / 401
  • II. Ueber die angeblichen Isomerien bei cyclischen Oxalsaeure-estern / 402
  • III. ε-Caprolactone / 407
  • IV. Polymers and Polyfunctionality / 409
  • Bibliography and Patents / 423
  • Authors Index / 433
  • Subject Index / 439

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この本の情報

書名 Collected papers of Wallace Hume Carothers on high polymeric substances; ed. by H. Mark [and] G. Stafford Whitby. New York, Interscience Publishers, 1940
著作者等 Carothers, Wallace Hume
シリーズ名 High polymers; a series of monographs on the chemistry, physics and technology of high polymeric substances; v. 1
巻冊次 [and] G. Stafford Whitby. New York, Interscience Publishers, 1940
出版元 Gakujutsu Bunken Shuppansha
刊行年月 1943]
言語 英語
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