The theory of organic chemistry : an advanced course

by Gerald E.K. Branch, Melvin Calvin

[目次]

• CONTENTS
• PREFACE / 5
• I. THE DEVELOPMENT OF STRUCTURAL CHEMISTRY / 1
• 1. Valence / 1
• 2. Structural Isomerism / 6
• 3. The Persistence of Structure / 6
• 4. Structural Analogy / 10
• 5. Structural Iteration / 12
• 6. Tautomerism / 14
• 7. Stereoisomerism / 16
• 8. The Constancy of Valence / 20
• II. ATOMIC STRUCTURE / 26
• 9. The Nuclear Atom / 26
• 10. The Lewis Atom / 27
• 11. The Quantum Theory of the Atom / 28
• III. MOLECULAR STRUCTURE / 38
• 12. Electronic Structural Formulas / 38
• 13. The Electron Pair Bond in Quantum Mechanics / 46
• IV. GROUP INTERACTION / 62
• 14. Group Interactions without Considering Resonance / 62
• 15. Conjugation / 67
• 16. Resonance and Mesomerism / 70
• V. PHYSICAL PROPERTIES / 91
• 17. Bond Distances and Angles / 92
• 18. Dipole Moments / 126
• 19. Raman Spectra and Force Constants / 151
• 20. Color / 155
• VI. EQUILIBRIUM-ACID STRENGTH / 183
• 21. Equilibrium / 183
• 22. Acids and Bases / 186
• 23. Acid Strength and Structure / 188
• 24. Acids without Resonance / 201
• 25. The Fatty Acids / 217
• 26. Unsaturated Acids / 233
• 27. The Aromatic Acids / 240
• 28. Miscellaneous Acids / 265
• VII. ENERGY RELATIONSHIPS IN SOME OTHER REACTIONS / 271
• 29. Ionic Resonance and the Heat of Formation / 271
• 30. Valence Bond Resonance and Heat of Formation / 272
• 31. Tautomerism / 281
• 32. Oxidation‐Reduction Potentials / 303
• 33. Free Radicals / 317
• 34. cis‐trans Isomerism of Olefins / 339
• 35. Equilibrium in the Addition to the Double Bond / 343
• VIII. THE RATE FACTOR IN CHEMICAL BEHAVIOR / 352
• 36. The Variation of Rate with Concentration / 353
• 37. The Temperature Coefficient of Reaction Rate / 367
• 38. Transition state / 376
• 39. Molecular association / 384
• 40. The Quantum Mechanical Treatment / 387
• IX. THE REACTIONS OF ACIDS AND BASES WITH NEUTRAL SUBSTANCES-THREE‐CENTER REACTIONS / 393
• 41. The Mechanisms of the Reactions / 394
• 42. The Strength of the Reacting Acid or Base(C) / 408
• 43. The Strength of the Product Acid or Base(A) / 423
• 44. The Middle Group(B)in the Three‐Center Reaction / 426
• 45. Inductive and Tautomeric Effects / 428
• 46. The Effect of Branching Chains / 430
• 47. The Effect of Resonance on Reaction Rate / 434
• 48. Steric Effects / 443
• X. REACTIONS OF THE DOUBLE BOND / 449
• 49. The Ethylenic Double Bond / 451
• 50. The Carbonyl Double Bond / 457
• 51. Conjugate Systems / 467
• 52. Substitution Reactions of Benzene / 470
• 53. Four‐Center Reactions / 487
• AUTHOR INDEX / 493
• SUBJECT INDEX / 499

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