Electronic structure and chemical binding : with special reference to inorganic chemistry

by Oscar Knefler Rice

[目次]

• CONTENTS
• PREFACE / 5
• TABLES / 8
• CHAPTER I DEVELOPMENT OF THE ATOMIC THEORY IN CHEMISTRY / 1
• CHAPTER II THE CONSTITUTION OF MATTER / 10
• CHAPTER III WAVE AND CORPUSCULAR PROPERTIES OF RADIATION AND MATTER / 25
• CHAPTER IV ELEMENTARY QUANTUM THEORY / 36
• CHAPTER V THE HYDROGEN ATOM / 60
• CHAPTER VI ELECTRON SPIN,ANGULAR MOMENTUM,AND MAGNETIC MOMENT / 75
• CHAPTER VII MANY ELECTRON ATOMS AND THE PERIODIC SYSTEM / 84
• CHAPTER VIII SOME PROPERTIES OF THE ELEMENTS AND THEIR CONNECTION WITH ELECTRON STRUCTURE / 95
• CHAPTER IX MOLECULAR POTENTIAL-ENERGY CURVES AND MOLECULAR MOTION / 104
• CHAPTER X THE HYDROGEN MOLECULE / 125
• CHAPTER XI THEORIES OF VALENCE / 151
• CHAPTER XII TRANSITION FROM COVALENT TO IONIC BINDING IN SIMPLE GASEOUS COMPOUNDS / 163
• CHAPTER XIII THE NATURE OF THE SOLID STATE / 205
• CHAPTER XIV IONIC CRYSTALS / 212
• CHAPTER XV FURTHER PROPERTIES OF COVALENT BONDS / 262
• CHAPTER XVI COMPLEX COMPOUNDS AND COMPLEX CRYSTALS,INCLUDING ATOMIC CRYSTALS / 286
• CHAPTER XVII MOLECULAR CRYSTALS / 354
• CHAPTER XVIII METALLIC CRYSTALS / 370
• CHAPTER XIX THE STRUCTURE OF WATER,HYDRATES,AND AQUEOUS SOLUTIONS / 392
• APPENDICES
• I. SOME DEFINITIONS AND THEOREMS OF CLASSICAL MECHANICS / 443
• II. THE PRINCIPLES OF EQUILIBRIUM / 454
• III. ELECTRICAL FORCES / 462
• IV. SOME REMARKS ON THE GEOMETRY OF MOLECULES AND CRYSTALS / 469
• V. GENERAL REFERENCES / 476
• AUTHOR INDEX / 479
• SUBJECT INDEX / 485
• FORMULA AND SUBSTANCE INDEX / 501
• TABLES
• 1. PERIODIC TABLE AND OUTER ELECTRONS OF THE ELEMENTS / 91
• 2. VALUES OF n* / 96
• 3. VALUES OF n* FOR SODIUM / 96
• 4. IONIZATION POTENTIALS / 98f.
• 5. ELECTRON AFFINITIES / 101
• 6. DEGREE OF DISSOCIATION OF H2 / 146
• 7. ENERGY OF DISSOCIATION FOR DIATOMIC MOLECULES / 165
• 8. r[e] FOR DIATOMIC MOLECULES / 165
• 9. ELECTRONEGATIVITY VALUES / 169
• 10. IONIC POLARIZABILITIES / 178
• 11. BOND ENERGIES IN THE NORMAL SATURATED HYDROCARBONS / 187
• 12. BOND ENERGIES,CALCULATED NONPOLAR BOND ENERGIES,AND△VALUES / 190
• 13. THERMOCHEMICAL DATA USED IN THE CALCULATION OF BOND ENERGIES / 192f.
• 14. ELECTRONEGATIVITIES / 196
• 15. SOME DIPOLE MOMENTS / 199
• 16. IONIC RADII / 220
• 17. CALCULATED AND OBSERVED DISTANCES IN ALKALI HALIDES / 221
• 18. VALUES OF THE MADELUNG CONSTANT / 225
• 19. DISTANCES FOR ALKALINE EARTH OXIDES,ETC. / 232
• 20. BORN-HABER CYCLE FOR THE ALKALI HALIDES / 235
• 21. BORN-HABER CYCLE FOR CUPROUS,SILVER AND THALLOUS HALIDES / 238
• 22. RESULTS OF THE APPLICATION OF THE BORN-HABER CYCLE TO HALIDE CRYSTALS / 239
• 23. BORN-HABER CYCLE FOR ALKALINE EARTH OXIDES,ETC. / 240
• 24. RESULTS OF THE APPLICATION OF THE BORN-HABER CYCLE TO OXIDES,SULFIDES,AND SELENIDES / 242
• 25. APPLICATION OF THE BORN-HABER CYCLE TO THE ALKALI HYDRIDES / 243
• 26. CALCULATED HEAT ABSORBED ON FORMATION OF SUBHALIDES / 246
• 27. PROPERTIES OF GASEOUS ALKALI HALIDES AND HYDRIDES / 253
• 28. PROPERTIES OF AMMONIUM HALIDES / 255
• 29. BOND DISTANCES AND ANGLES IN UNSYMMETRICAL MOLECULES / 270f.
• 30. TYPES OF BINDING IN COMPLEX IONS FROM THE MAGNETIC CRITERION / 294
• 31. SHAPES OF CERTAIN IONS IN CRYSTALS / 308
• 32. RATIOS OF RADII:CATION/OXYGEN.COORDINATION NUMBERS IN COMPLEX CRYSTALS AND OXYGEN IONS / 317
• 33. COVALENT RADII / 319
• 34. BOND DISTANCES AND RADIUS SUMS IN METHYL COMPOUNDS / 322
• 35. BOND DISTANCES IN HALIDES / 323
• 36. DISTANCES IN CRYSTALS / 327ff.
• 37. INTERATOMIC DISTANCES IN ISOSTERIC CRYSTALS WITH COVALENT BINDING / 333
• 38. PROPERTIES ILLUSTRATING THE TRANSITION BETWEEN IONIC AND COVALENT BINDING / 335
• 39. THEORETICAL AND EMPIRICAL HEATS OF SUBLIMATION / 357
• 40. PROPERTIES OF HYDROGEN HALIDES / 363
• 41. BINDING ENERGIES OF ALKALI AND ALKALINE EARTH METALS / 373
• 42. CRYSTAL STRUCTURES OF CERTAIN ELEMENTS / 378
• 43. SPECIFIC CONDUCTANCE OF METALLIC COMPOUNDS / 381
• 44. HEATS OF FORMATION OF METALLIC COMPOUNDS / 381
• 45. COMPOSITIONS OF ALLOYS / 384
• 46. ABSOLUTE BOILING POINTS / 396
• 47. HEATS OF SOLUTION OF ALKALI HALIDES / 400
• 48. HEATS OF SOLUTION OF ALKALI AND HALOGEN IONS / 402
• 49. HEATS OF SOLUTION OF VARIOUS IONS / 403
• 50. ENTROPIES OF SOLUTION OF SOLID SALTS / 407
• 51. ENTROPIES OF IONIZATION OF SOLID SALTS TO FORM GASEOUS IONS / 408
• 52. ENTROPIES OF SOLUTION OF GASEOUS IONS / 408
• 53. APPARENT IONIC VOLUMES IN SOLUTION / 410
• 54. ANALYSIS OF OXIDATION REACTIONS,I / 439
• 55. ANALYSIS OF OXIDATION REACTIONS,II / 440

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