Preparation and reactions of titana-, zircona- and hafnacycles

[目次]

  • Contents
  • Abbreviations / p1
  • General Experimental / p2
  • Chapter1 General Introduction / p1
  • Zirconocene(II) Species in Organic Synthesis / p4
  • Applications of Zirconacycles / p10
  • Generation of Hafnocene(II) Species and Preparation of Hafnacycles / p12
  • Generation of Titanocene(II) Species and Preparation of Titanacycles / p16
  • Purpose and Scope of This Dissertation / p21
  • References and Notes / p22
  • Chapter2 Highly Selective Monofunctionalization of Zirconacyclopentanes and Dialkylzirconocene Complexes / p27
  • Introduction / p28
  • Results and Discussion / p29
  • Experimental Section / p39
  • References and Notes / p44
  • Chapter3 Highly Regio- and Diastereoselective Carbon-Carbon Bond Formation Reaction of Zirconacyclopentanes Using Copper Salt / p46
  • Introduction / p47
  • Results and Discussion / p48
  • Experimental Section / p64
  • References and Notes / p74
  • Chapter4 Reaction of Alkenylzirconocene with Dialkylzirconocene: Unexpected Formation of Bimetallic (μ-Alkynyl)zirconocene Complexes / p76
  • Introduction / p77
  • Results and Discussion / p77
  • Experimental Section / p88
  • References and Notes / p90
  • Chapter5 Preparation and Reactions of Cp₂HfRCl,Cp₂HfRR'and Hafnacylopentene / p91
  • Introduction / p92
  • Results and Discussion / p93
  • Experimental Section / p100
  • References and Notes / p104
  • Chapter6 Reaction of Cp₂TiCl₂ with EtMgBr and Alkynes / p105
  • Introduction / p106
  • Results and Discussion / p106
  • Experimental Section / p110
  • References and Notes / p112
  • Chapter7 Preparation and Reactivity of Zirconocene(II) Complexes Stabilized by Olefinic Phosphine Ligands / p114
  • Introduction / p115
  • Results and Discussion / p117
  • Experimental Section / p120
  • References and Notes / p124
  • Chapter8 Properties of Zirconacyclopentenes with Alkynyl Substituents at the α-Position / p126
  • Introduction / p127
  • Results and Discussion / p128
  • Experimental Section / p132
  • References and Notes / p134
  • Chapter9 Summary / p136
  • List of Publications / p139
  • List of Presentations / p142
  • Acknowledgments / p144

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書名 Preparation and reactions of titana-, zircona- and hafnacycles
著作者等 西原 康師
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