Synthesis of a novel reaction field based on capsule-shaped molecules having endohedral functionalities

[目次]

  • Contents / p1
  • ChapterI General Introduction
  • I.1 Supramolecular Chemistry of Cage Compounds / p1
  • I.2 Reactions of Endohedral Functionalities / p10
  • I.3 Concave Functionalities in Cyclophanes / p13
  • I.4 Stabilization of Highly Reactive Chemical Species by Steric Protection / p16
  • I.5 Concept of the Novel Reaction Field / p19
  • References and Notes / p22
  • ChapterII Design,Syntheses,and Structures of Novel Capsule-shaped Molecules of Type α
  • II.1 Introduction / p27
  • II.2 Design of Novel Capsule-shaped Molecules / p29
  • II.3 Synthetic Strategy of Capsule-shaped Molecules / p33
  • II.4 Preparation of a Capping Unit / p35
  • II.5 Preparation of Bottom Units / p37
  • II.6 Synthesis of Capsule-shaped Molecules of Type α / p38
  • II.7 ¹H NMR Spectral Properties of Capsule-shaped Molecules / p41
  • II.8 Molecular Mechanics Calculations of Concave and Convex Isomers / p44
  • II.9 Thermal Isomerization between Concave and Convex Isomers / p46
  • Experimental / p55
  • References and Notes / p80
  • Chapter III Design,Syntheses,and Structures of Novel Capsule-shaped Molecules of Types β and γ
  • III.1 Introduction / p83
  • III.2 Design of Capsule-shaped Molecules of Types β and γ / p83
  • III.3 Preparation of Capping Units / p84
  • III.4 Preparation of Bottom Units / p87
  • III.5 Synthesis of Capsule-shaped Molecules of Types β and γ / p89
  • III.6 ¹H NMR Spectral Properties of Capsule-shaped Molecules / p94
  • III.7 Structure of the Methylthioacetyl-substituted Capsule-shaped Molecule in Solution / p94
  • Experimental / p100
  • References and Notes / p121
  • Chapter IV Reactions of Endohedral Functionalities
  • IV.1 Introduction / p122
  • IV.2 Reaction of Endohedral Bromide 1 with Butyllithium / p122
  • IV.3 Reaction of Endohedral Ester 2 with Red-Al® / p124
  • Experimental / p127
  • References and Notes / p129
  • Chapter V Photochemical Reactions of a Methylthioacetyl-substituted Capsule-shaped Molecule
  • V.1 Introduction / p130
  • V.2 Photochemical Reaction of the Methylthioacetyl-substituted Capsule-shaped Molecule 10 in the Presence of Danishefsky's Diene / p137
  • V.3 Spectral Properties of the Mono-substituted Stable Simple Enol 15 / p140
  • V.4 Photochemical Reaction of the Methylthioacetyl-substituted Capsule-shaped Molecule 10 in the Absence of Danishefsky's Diene / p144
  • Experimental / p147
  • References and Notes / p151
  • Acknowledgment / p153

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書名 Synthesis of a novel reaction field based on capsule-shaped molecules having endohedral functionalities
著作者等 渡邊 総一郎
書名別名 空孔内に官能基を有するカプセル型分子を用いた新規な反応場の開発
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