Kinetics of liquid-liquid catalyzed reaction

[目次]

  • TABLE OF CONTENTS / p1
  • INTRODUCTION / p1
  • 1.Review of Previous Studies / p4
  • 2.Summary of Results in This Work / p9
  • Literature Cited / p14
  • PART I HETEROGENEOUS LIQUID-LIQUID REACTION WITH PHASE TRANSFER CATALYST / p19
  • Chapter I Distribution and Dissociation Equilibria of Phase Transfer Catalysts and Their Aqueous-Phase Mass Transfer / p21
  • 1.Introduction / p21
  • 2.Distribution and Dissociation Equilibria / p22
  • 3.Mass Transfer / p51
  • 4.Conclusions / p56
  • Nomenclature / p57
  • Literature Cited / p59
  • Chapter Ⅱ Alkaline Hydrolysis of n-Butyl Acetate with Phase Transfer Catalyst Aliquat 336 / p61
  • Ⅱ-l Kinetics of Alkaline Hydrolysis of n-Butyl Acetate without Catalyst / p61
  • Ⅱ-2 Kinetics of Alkaline Hydrolysis of n-Butyl Acetate with Aliquat336 / p72
  • Chapter Ⅲ Synthesis of Triphenyl Phosphate with Tetrabutylammonium Bromide / p93
  • 1.Introduction / p93
  • 2.Experimental / p94
  • 3.Reaction Model and Analytical Procedure / p96
  • 4.Physical Properties / p102
  • 5.Results and Discussion / p103
  • 6.Conclusions / p107
  • Nomenclature / p108
  • Literature Cited / p109
  • Chapter Ⅳ Synthesis of Benzyl Benzoate with Tetrabutylammonium Bromide / p111
  • 1.Introduction / p111
  • 2.Experimental / p111
  • 3.Analytical Procedure / p112
  • 4.Physical Properties / p115
  • 5.Results and Discussion / p116
  • 6.Conclusions / p119
  • Nomenclature / p120
  • Literature Cited / p121
  • Chapter V Oxidation of Benzyl Alcohol Using Hypochlorite Ion / p123
  • 1.Introduction / p123
  • 2.Experimental / p124
  • 3.Reaction Model and Analytical Procedure / p127
  • 4.Physical Properties / p131
  • 5.Results and Discussion / p133
  • 6.Conclusions / p137
  • Nomenclature / p138
  • Literature Cited / p139
  • PART Ⅱ HETEROGENEOUS LIQUID-LIQUID REACTION WITH INVERSE PHASE TRANSFER CATALYST / p141
  • Chapter I Equilibrium Relation of Inverse Phase Transfer Catalyst 4-Dimethylaminopyridine / p143
  • 1.Introduction / p143
  • 2.Analytical Procedure / p143
  • 3.Experimental / p146
  • 4.Results and Discussion / p148
  • 5.Conclusions / p155
  • Nomenclature / p156
  • Literature Cited / p157
  • Chapter Ⅱ Synthesis of Hippuric Acid with 4-Dimethylaminopyridine / p159
  • 1.Introduction / p159
  • 2.Experimental / p160
  • 3.Reaction Model and Analytical Procedure / p160
  • 4.Physical Properties / p165
  • 5.Results and Discussion / p166
  • 6.Conclusions / p170
  • Nomenclature / p170
  • Literature Cited / p171
  • Chapter Ⅲ Protection of Amino Group of DL-Serine Using Carbobenzoxy Chloride / p173
  • 1.Introduction / p173
  • 2.Experimental / p176
  • 3.Analytical Procedure / p176
  • 4.Physical Properties / p178
  • 5.Results and Discussion / p179
  • 6.Conclusions / p182
  • Nomenclature / p183
  • Literature Cited / p184
  • PART Ⅲ HETEROGENEOUS LIQUID-LIQUID REACTION WITH MICELLAR CATALYST / p185
  • Chapter I Mass Transfer of Solubilized Solute in Aqueous Micellar Solution / p187
  • 1.Introduction / p187
  • 2.Mass Transfer Model / p187
  • 3.Experimental / p191
  • 4.Physical Properties and System Parameters / p193
  • 5.Results and Discussion / p195
  • 6.Conclusions / p206
  • Nomenclature / p207
  • Literature Cited / p208
  • Chapter Ⅱ Micellar-Catalyzed Oximation of Cyclohexanone by Sodium Dodecyl Sulfate / p209
  • Ⅱ-I Kinetics of Oximation of Cyclohexanone Using Aqueous Hydroxyl Ammonium Sulfate Solution without Catalyst / p209
  • Ⅱ-2 Micellar-Catalyzed Oximation of Cyclohexanone by Sodium Dodecyl Sulfate / p226
  • Chapter Ⅲ Micellar-Catalyzed Alkaline Hydrolysis of n-Butyl Acetate by Cetyltrimethylammonium Bromide / p249
  • 1.Introduction / p249
  • 2.Modelling of Micellar Catalysis / p249
  • 3.Experimental / p253
  • 4.Physical Properties and System Parameters / p254
  • 5.Results and Discussion / p257
  • 6.Conclusions / p264
  • Nomenclature / p264
  • Literature Cited / p266
  • ACKNOWLEDGMENT / p267

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書名 Kinetics of liquid-liquid catalyzed reaction
著作者等 中村 秀美
書名別名 液-液触媒反応の速度論的解析
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