A study of nitrogen-bridged macrotricyclic compounds syntheses, structures and inclusion phenomena

[目次]

  • Contents
  • 1.Introduction / p1
  • 2.Syntheses of Aza-bridged Cage Compounds / p8
  • 2-1.General methods / p10
  • 2-2.Cage compounds containing rigid units / p15
  • 2-3.Cage compounds containing functional groups / p17
  • 2-4.Cage compounds containing more flexible units / p20
  • 2-5.Structures of cage compounds / p23
  • 3.Properties of Compounds 8a and 9a / p29
  • 3-1.X-ray structural determinations of K⁺ ⊂9a and NH₄⁺ ⊂9a / p30
  • 3-2.Cu⁺ complex of 8a / p37
  • 3-3.Structure of 2Ag⁺ ⊂9a・2X⁻:(X=NO₃,BF₄) / p40
  • 3-4.Synthesis of Ag⁺ ⊂9a・Br⁻・H₂O:Attempt to remove silver ions with halides / p44
  • 3-5.Stabilities of 2Ag⁺ ⊂9a and Ag⁺ ⊂9a against light:Irradiation of light to the solutions of silver complexes of 9a / p49
  • 3-6.Electrochemical properties of 2Ag⁺ ⊂9a and Ag⁺ ⊂9a:Cyclic voltammetry measurements of silver complexes of 9a / p51
  • 3-7.Preparations of guest-free 8a and 9a / p51
  • 3-8.Interactions of compound 9a with neutral guest species / p55
  • 3-9.Property of 9a as a base / p62
  • 3-10.Complexes of 9a with other guests / p64
  • 4.Properties of Cage Compound containing six fluorine atoms / p69
  • 4-1.Affinities toward cations / p70
  • 4-2.NMR spectroscopic investigations of 12b on complexation / p72
  • 4-3.Structures of compounds 12b and K⁺ ⊂12b / p76
  • 5.Conclusion / p81
  • 6.Experimental Section / p83
  • 7.References and Notes / p100
  • 8.Acknowledgements / p107

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この本の情報

書名 A study of nitrogen-bridged macrotricyclic compounds syntheses, structures and inclusion phenomena
著作者等 今 徳義
書名別名 含窒素多架橋大環状トリサイクリック化合物に関する研究
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