Formation and reactions of stannanethiones and stannaneselones

[目次]

  • Contents / p2
  • Chapter1 General Introduction / p1
  • 1.1 General Introduction / p2
  • 1.2 References and Notes / p15
  • Chapter2 Preparation of 1,2,3,4,5-TetrachalcogenastannoIanes / p20
  • 2.1 Introduction / p21
  • 2.2 Synthesis of Dichlorostannanes and Dihydrostannanes / p22
  • 2.3 Synthesis of Tetrachalcogenastannolanes via Direct Chalcogenation / p23
  • 2.4 Synthesis of Tetrachalcogenastannolanes via Lithiation Followed by Chalcogenation / p25
  • 2.5 Structures of Tetrachalcogenastannolanes / p28
  • 2.6 Experimental / p38
  • 2.7 References and Notes / p51
  • Chapter3 1,2,4,3-Trichalcogenastannolanes / p54
  • 3.1 Introduction / p55
  • 3.2 Reactions of Tetrachalcogenastannolanes with Diphenyldiazomethane / p55
  • 3.3 Dechalcogenation of Tetrachalcogenacyclohexanes by Hexamethyl-phosphorous Triamide / p57
  • 3.4 Mechanism of the Formation of Trichalcogenastannolanes / p58
  • 3.5 Experimental / p61
  • 3.6 References and Notes / p66
  • Chapter4 Formation and Reactions of Stannanethiones and Stannaneselones via Dechalcogenation of Tetrachalcogenastannolanes / p67
  • 4.1 Introduction / p68
  • 4.2 Dechalcogenation of Tetrachalcogenastannolanes with Hexamethyl-phosphorous Triamide / p68
  • 4.3 Dechalcogenation of Tetrachalcogenastannolanes with Triphenylphosphine / p70
  • 4.4 Dechalcogenation with Trivalent Phosphorus Compounds in the Presence of Epoxides / p73
  • 4.5 Dechalcogenation with Trivalent Phosphorus Compounds in the Presence of a Diene / p76
  • 4.6 Structures of Dichalcogenadistannetanes and Oxaselenastannolane / p77
  • 4.7 Experimental / p93
  • 4.8 References and Notes / p107
  • Chapter5 Formation of Stannanethiones and Stannaneselones via Thermolysis / p109
  • 5.1 Introduction / p110
  • 5.2 Thermolysis of Trichalcogenastannolanes in the Presence of an Acetylene Derivative / p110
  • 5.3 Reaction Mechanism / p113
  • 5.4 Thermal Decomposition of a Dithiastannetane in the Presence of a Diene / p116
  • 5.5 Structures of 1,2-Chalcogenastannetes / p119
  • 5.6 Experimental / p125
  • 5.7 References and Notes / p131
  • Chapter6 Transition Metal Complexes Bridged by Stannanethiones and Stannaneselones / p132
  • 6.1 Introduction / p133
  • 6.2 Reaction of a Tetrathiastannolane with W(C0)₆ and Structure of the Product / p135
  • 6.3 Reaction of Tetrachalcogenastannolanes with Ru₃(C0)₁₂ / p138
  • 6.4 Reaction of Tetrachalcogenastannolanes with Os₃(CO)₁₂ / p145
  • 6.5 Plausible Mechanism for the Formation of the Transition Metal Complexes / p158
  • 6.6 Experimental / p160
  • 6.7 References and Notes / p169
  • List of Publications / p174
  • Acknowledgment / p176

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この本の情報

書名 Formation and reactions of stannanethiones and stannaneselones
著作者等 松橋 泰典
書名別名 スタナンチオン及びスタナンセロンの生成と反応
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