Stereoselective reactions of organocopper and organozinc reagents

[目次]

  • 論文目録
  • Table of Contents
  • Chapter1 General Introduction.Development of Carbon-Carbon Bond Formation Reactions and Asymmetric lnduction / p1
  • 1.1 Nucleophilic Addition to α-Chiral Carbonyl Compound / p2
  • 1.2 Asymmetric Induction in the Nucleophilic Addition to Chiral Olefins / p5
  • Chapter2 High Diastereoselectivity in[化学式]-Allylation of Copper-Zinc Reagents / p14
  • 2.1 [化学式]Allylation with δ-Substituted Allylic Chlorides / p14
  • 2.2 δ-Substituted Allylic Chloride. Choice of the Substrate / p19
  • 2.3 [化学式] Allylation of δ-Alkoxyallylic Chlorides / p24
  • 2.4 [化学式] Allylation of δ-Substituted Allylic Chlorides.Steric Effect at Chiral Center / p33
  • 2.5 [化学式] Allylation of Silylcopper Reagent / p40
  • 2.6 Structure Determination / p41
  • 2.7 Conclusion / p47
  • 2.8 Experimental Section / p49
  • References / p76
  • Chapter3 0n the Nature of the Copper-Based[化学式]-Selective Reagents / p79
  • 3.1 lntroduction / p79
  • 3.2 Experimental Method / p83
  • 3.3 NMR Analysis of Copper-Zinc and Copper-Titanium Reagents / p85
  • 3.4 Reactivity Analysis of the Copper-Zinc and the Copper-Titanium Reagents / p94
  • 3.5 Conclusion / p98
  • References / p100
  • Chapter4 Copper-Catalyzed Reactions of Organotitanium Reagents.Highly Selective[化学式]-Allylation and Conjugate Addition / p102
  • 4.1 Introduction / p102
  • 4.2 [化学式]-Allylation Reaction of Organozinc-Based Catalytic Organocopper Reagents / p103
  • 4.3 [化学式]-Allylation of Organotitanium-Based Catalytic Organocopper Reagents / p106
  • 4.4 Conjugate Addition of Organotitanium-Based Catalytic Organocopper Reagents in the Presence of Me₃SiCl / p112
  • 4.5 Conclusion / p115
  • 4.6 Experimental Section / p116
  • References / p129
  • Chapter5 [化学式]-Allylation Reaction of Organozinc Reagents.Highly Regio-and Diastereoselective Reaction / p133
  • 5.1 lntroduction / p133
  • 5.2 [化学式]-Allylation Reaction of Organozinc Reagents / p135
  • 5.3 Asymmetric Induction in the[化学式]-Allylation of Dialkylzinc Reagents / p138
  • 5.4 [化学式]-Allylation of δ-Alkoxy Substituted Allylic Chlorides / p144
  • 5.5 Conclusion / p146
  • 5.6 Experimental Section / p147
  • References / p159
  • Chapter6 Stereochemistry of the[化学式]-Allylation Reaction / p161
  • 6.1 Observed Stereoselectivity in the Present[化学式]-Allylation Reactions / p161
  • 6.2 Distinctive Stereochemical Properties of the[化学式]-Allylation Reaction / p164
  • 6.3 Mechanism of the Present[化学式]-Allylation / p168
  • 6.4 Nucleophilic Carbon Mechanism.Explanation of Stereochemical Behavior / p171
  • 6.5 Conclusion / p178
  • References / p179
  • Chapter7 1,4-Asymmetric Induction in the 1,2-Addition to α,β-Unsaturated Aldehydes in the Presence of Chlorosilane.Vinylogous Cram's Rule / p181
  • 7.1 lntroduction / p181
  • 7.2 Vinylogous Cram's Rule / p182
  • 7.3 Conclusion / p188
  • 7.4 Experimental Section / p189

「国立国会図書館デジタルコレクション」より

この本の情報

書名 Stereoselective reactions of organocopper and organozinc reagents
著作者等 荒井 雅之
書名別名 有機銅試薬及び有機亜鉛試薬を用いた立体選択的反応
この本を: 
このエントリーをはてなブックマークに追加

このページを印刷

外部サイトで検索

この本と繋がる本を検索

ウィキペディアから連想