Studies of the development of rare-earth silicates based on new solid state electrolytes and their application to concentration cell type gas sensors

[目次]

  • Contents
  • Chapter1 General introduction / p1
  • 1-1.Outline and the present situation,solid electrolytes / p1
  • 1-2.Summary and the present status of CO₂ gas sensors based on solid electrolytes / p7
  • 1-3.Purpose and outline of this study / p10
  • Chapter2 Ionic conductivity of ceramics prepared by sintering of M₂CO₃・RE₂O₃-2SiO₂(M=Li,Na,K,Rb,Cs RE=La,Nd,Sm,Gd,Dy,Y,Ho,Er,Yb)mixtures / p17
  • 2-1.Introduction / p17
  • 2-2.Experimental and analysis of electrical properties / p18
  • 2-3.Results and discussion / p24
  • 2-4.Summary / p40
  • Chapter3 Morphology and ionic conductivity of potassium-samarium-silicates,K₂O-Sm₂O₃-nSiO₂(n=1-14) / p41
  • 3-1.Introduction / p41
  • 3-2.Experimental / p41
  • 3-3.Results and discussion / p43
  • 3-4.Summary / p53
  • Chapter4 Ionic conductivity of rare-earth silicate,RE₁₀Si₆0₂₇(RE=La,Nd,Sm,Gd,Dy,Y,Ho,Er,Yb) / p55
  • 4-1.Introduction / p55
  • 4-2.Experimental / p55
  • 4-3.Results and discussion / p57
  • 4-4.Summary / p68
  • Chapter5 Application of the concentration cell type CO₂ gas sensor of the alkali-metal rare-earth silicate solid electrolyte / p70
  • 5-1.Introduction / p70
  • 5-2.Thermodynamic analysis of electromotive force characteristics of the concentration cell type gas sensor / p70
  • 5-3.CO₂ gas sensor using the potassium ionic conductor,K₂O-Sm₂O₃-6SiO₂ / p71
  • 5-4.CO₂ gas sensor using the lithium ionic conductor,Li₂O-RE₂O₃-2SiO₂(RE=La,Nd,Sm) / p80
  • 5-5.CO₂ gas sensor using the layer type ionic conductor,Li₂0-Sm₂0₃-2Si0₂+(Zr0₂)₀․₉₂(Yb₂0₃)₀․₀₈ / p84
  • 5-6.Summary / p88
  • Chapter6 Concluding remarks / p90
  • References / p93

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この本の情報

書名 Studies of the development of rare-earth silicates based on new solid state electrolytes and their application to concentration cell type gas sensors
著作者等 中山 享
書名別名 希土類-ケイ酸塩からなる新しい固体電解質の開発と濃淡電池型ガスセンサへの応用に関する研究
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